1.0 2016-09-30 23:16:10 UTC 2020-06-04 20:32:48 UTC BMDB0005384 BMDB05384 TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] belongs to the class of organic compounds known as triacylglycerols. These are glycerides consisting of three fatty acid chains covalently bonded to a glycerol molecule through ester linkages. Thus, TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] is considered to be a triradylglycerol lipid molecule. TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] is a very hydrophobic molecule, practically insoluble (in water), and relatively neutral. TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] can be biosynthesized from DG(16:0/18:1(9Z)/0:0) and linoleoyl-CoA through the action of the enzyme diacylglycerol O-acyltransferase. In cattle, TG(16:0/18:1(9Z)/18:2(9Z,12Z))[iso6] is involved in the metabolic pathway called de novo triacylglycerol biosynthesis TG(16:0/18:1(9Z)/18:2(9Z,12Z)) pathway. 1-linoleoyl-2-oleoyl-3-palmitoyl-glycerol TG(18:2/18:1/16:0) TG(18:2n6/18:1n9/16:0) TG(18:2w6/18:1w9/16:0) TG(52:3) Tag(18:2(9Z,12Z)/18:1(9Z)/16:0) Tag(18:2/18:1/16:0) Tag(18:2n6/18:1n9/16:0) Tag(18:2w6/18:1w9/16:0) Tag(52:3) Triacylglycerol(18:2(9Z,12Z)/18:1(9Z)/16:0) Triacylglycerol(18:2/18:1/16:0) Triacylglycerol(18:2n6/18:1n9/16:0) Triacylglycerol(18:2w6/18:1w9/16:0) Triacylglycerol(52:3) Triacylglycerol Triglyceride TG(18:2(9Z,12Z)/18:1(9Z)/16:0) 1-Palmitoyl-2-oleoyl-3-linoleoyl-glycerol TAG(16:0/18:1/18:2) TAG(16:0/18:1n9/18:2n6) TAG(16:0/18:1W9/18:2W6) TG(16:0/18:1/18:2) TG(16:0/18:1n9/18:2n6) TG(16:0/18:1W9/18:2W6) Tracylglycerol(16:0/18:1/18:2) Tracylglycerol(16:0/18:1n9/18:2n6) Tracylglycerol(16:0/18:1W9/18:2W6) Tracylglycerol(52:3) C55H100O6 857.3789 856.751990932 (2R)-3-(hexadecanoyloxy)-2-[(9Z)-octadec-9-enoyloxy]propyl (9Z,12Z)-octadeca-9,12-dienoate (2R)-3-(hexadecanoyloxy)-2-[(9Z)-octadec-9-enoyloxy]propyl (9Z,12Z)-octadeca-9,12-dienoate CCCCCCCCCCCCCCCC(=O)OC[C@H](COC(=O)CCCCCCC\C=C/C\C=C/CCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC InChI=1S/C55H100O6/c1-4-7-10-13-16-19-22-25-27-30-33-36-39-42-45-48-54(57)60-51-52(50-59-53(56)47-44-41-38-35-32-29-24-21-18-15-12-9-6-3)61-55(58)49-46-43-40-37-34-31-28-26-23-20-17-14-11-8-5-2/h16,19,25-28,52H,4-15,17-18,20-24,29-51H2,1-3H3/b19-16-,27-25-,28-26-/t52-/m1/s1 KGLAHZTWGPHKFF-RISKEULASA-N belongs to the class of organic compounds known as triacylglycerols. These are glycerides consisting of three fatty acid chains covalently bonded to a glycerol molecule through ester linkages. Organic compounds Lipids and lipid-like molecules Glycerolipids Triradylcglycerols Triacylglycerols Carbonyl compounds Carboxylic acid esters Fatty acid esters Hydrocarbon derivatives Lineolic acids and derivatives Organic oxides Tricarboxylic acids and derivatives Aliphatic acyclic compound Carbonyl group Carboxylic acid derivative Carboxylic acid ester Fatty acid ester Fatty acyl Hydrocarbon derivative Octadecanoid Organic oxide Organic oxygen compound Organooxygen compound Triacyl-sn-glycerol Tricarboxylic acid or derivatives Aliphatic acyclic compounds Triacylglycerols Solid logp 10.77 ALOGPS logs -8.11 ALOGPS logp 19.62 ChemAxon pka_strongest_basic -6.6 ChemAxon iupac (2R)-3-(hexadecanoyloxy)-2-[(9Z)-octadec-9-enoyloxy]propyl (9Z,12Z)-octadeca-9,12-dienoate ChemAxon average_mass 857.3789 ChemAxon mono_mass 856.751990932 ChemAxon smiles CCCCCCCCCCCCCCCC(=O)OC[C@H](COC(=O)CCCCCCC\C=C/C\C=C/CCCCC)OC(=O)CCCCCCC\C=C/CCCCCCCC ChemAxon formula C55H100O6 ChemAxon inchi InChI=1S/C55H100O6/c1-4-7-10-13-16-19-22-25-27-30-33-36-39-42-45-48-54(57)60-51-52(50-59-53(56)47-44-41-38-35-32-29-24-21-18-15-12-9-6-3)61-55(58)49-46-43-40-37-34-31-28-26-23-20-17-14-11-8-5-2/h16,19,25-28,52H,4-15,17-18,20-24,29-51H2,1-3H3/b19-16-,27-25-,28-26-/t52-/m1/s1 ChemAxon inchikey KGLAHZTWGPHKFF-RISKEULASA-N ChemAxon polar_surface_area 78.9 ChemAxon refractivity 263.04 ChemAxon polarizability 113.31 ChemAxon rotatable_bond_count 51 ChemAxon acceptor_count 3 ChemAxon donor_count 0 ChemAxon physiological_charge 0 ChemAxon formal_charge 0 ChemAxon number_of_rings 0 ChemAxon bioavailability 0 ChemAxon rule_of_five Yes ChemAxon ghose_filter Yes ChemAxon veber_rule Yes ChemAxon mddr_like_rule Yes ChemAxon Specdb::MsMs 1458038 Specdb::MsMs 1458039 Specdb::MsMs 1458040 Specdb::MsMs 1469300 Specdb::MsMs 1469301 Specdb::MsMs 1469302 Milk 275 +/- 16 uM Commercial 1% milk by LC-HRMS Foroutan A, Guo AC, Vazquez-Fresno R, Lipfert M, Zhang L, Zheng J, Badran H, Budinski Z, Mandal R, Ametaj BN, Wishart DS: Chemical Composition of Commercial Cow's Milk. J Agric Food Chem. 2019 Apr 17. doi: 10.1021/acs.jafc.9b00204. 30994344 Milk 431 +/- 7 uM Commercial 2% milk by LC-HRMS Foroutan A, Guo AC, Vazquez-Fresno R, Lipfert M, Zhang L, Zheng J, Badran H, Budinski Z, Mandal R, Ametaj BN, Wishart DS: Chemical Composition of Commercial Cow's Milk. J Agric Food Chem. 2019 Apr 17. doi: 10.1021/acs.jafc.9b00204. 30994344 Milk 1299 +/- 30 uM Commercial 3.25% milk by LC-HRMS Foroutan A, Guo AC, Vazquez-Fresno R, Lipfert M, Zhang L, Zheng J, Badran H, Budinski Z, Mandal R, Ametaj BN, Wishart DS: Chemical Composition of Commercial Cow's Milk. J Agric Food Chem. 2019 Apr 17. doi: 10.1021/acs.jafc.9b00204. 30994344 Milk 9.8 +/- 0.1 uM Commercial skim milk by LC-HRMS Foroutan A, Guo AC, Vazquez-Fresno R, Lipfert M, Zhang L, Zheng J, Badran H, Budinski Z, Mandal R, Ametaj BN, Wishart DS: Chemical Composition of Commercial Cow's Milk. J Agric Food Chem. 2019 Apr 17. doi: 10.1021/acs.jafc.9b00204. 30994344 25240361 FDB094311 A. Foroutan et al. The Chemical Composition of Commercial Cow's Milk (in preparation)